The starting point of thermodynamic logic is: 1) opposing perpetual motion. 2) The irreversibility of dynamics. Let's look at how to get Carnot efficiency = 1-T1/T2.
1.1 There are many kinds of type 2 perpetual motors, each of which is a natural phenomenon.
A) Machine A: against the irreversibility of thermodynamics (diffusion, heat conduction, friction, etc) - dynamics;
B) Machine B: Utilizing the Difference of Carnot Efficiency (Reversible Thermodynamics) - Thermodynamics
1.2 A and B belong to different disciplines. There is a parallel relationship between them and there is no logical mutual inevitability.
1.3. Logic of the Second Law of Thermodynamics:
Experience induction, deny that A machine==> B machine can not be manufactured==> All material Kano efficiency: 1-T1/T2.
1.4 The logic of the second law of thermodynamics violates the physical logic that A and B cannot be inferred from each other.
1.5 The second law of thermodynamics elevates the "irreversibility", which is in fact only a kinetic experience.
📷 Detailed discussion can be found in the following figure.
1. Logic of the Second Law of Thermodynamics: Subjectivism, Logical Jump, Interdisciplinary Argumentation.
2. New thermodynamics pursues universality, two theoretical cornerstones:
2.1 Boltzmann formula: ro=A*exp(-Mgh/RT) - Isotope centrifugal separation experiments show that it is suitable for gases and liquids.
2.2. Hydrostatic equilibrium: applicable to gases and liquids.
3. The second and third sonic virial coefficients of R143a derived from the new thermodynamics are in agreement with the experimental results.
3.1. The third velocity Virial coefficient derived is in agreement with the experimental data, which shows that the theory is still correct when the critical density is reached.
4. See Appendix Pictures and Documents for details.