I think that this question is an important topic for a research project.
Maybe you'll find this paper interesting:
http://www.nature.com/nnano/journal/v7/n8/abs/nnano.2012.64.html
THIS MIGHT BE RELEVANT TOO IEEE Transactions in Nanobioscience vol 4 p201-2
Check this out: Cell specific cytotoxicity and uptake of graphene nanoribbons, Biomaterials, Volume 34, Issue 1, January 2013, Pages 283–293
http://www.sciencedirect.com/science/article/pii/S0142961212010654
This is the inquiry, that all of us have to question before we design a nanomaterial, I think the effects would be big, because the use of this nanomaterials are increasing very rapidly, and until now I didn´t Know any legislation or prohibition about their use.
So the ideal is that, at the time we are synthesizing new materials, we are doing toxicological assays.
I am doing that, because I think is part of our research and part of our responsability, what happened next to the environment.
If biodegradable i think no harm. The fear is from leaking genes with gene therapy where different antibiotic resistant gene are used... Personal opinion
This is a huge area of debate/investigation - see for example the recently completed EU project http://www.nanoimpactnet.eu/ and reports therein
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