It is possible for amide C-N bond cleavage in Ru(II) complexes? The ligand having electron withdrawing substituent? What is the possible reasons?

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Kyle A. Grice

Thioamides are better ligands and more likely to cleave than amides. The Ru could activate the thioamide to nucleophilic attack by solvent or adventitious water if you in a non-aqueous solution.

Ramasamy Raj Kumar

Dear Kyle A.Grice

Greetings!

Thanks for your suggestions.

Kindly explain the mechanism behind the amide C-N bond cleavage in ruthenium complexes.

Arnab Biswas

amide bond cleavage in general is tough..for your case I would suggest you try the experiment once and draw your conclusions based on your observations

Bojidarka B. Ivanova

Mr. Kumar,

Can you provide experimental spectrsocopic data about such as cleavage?