I answer yes, the solution is to play on the pressure and temperature of the wastewater,
The emulsions are thermodynamically unstable, however they may be kinetically stable over a significant period of time, which determines their lifetime.
On the fact that you have more oil emulsified it is normal because it is the waste water the percentage of water is higher than that of the oil. What is not to exclude is also to look at the type of organic and mineral products contained in these same waters because these have an obvious effect on the emulsion process.