Is there any difference in chemical properties/ reactivity, between Lewis Acid site (LAS) generated by (Al) or Lewis Acid site generated by (Sn) in Zeolite (MFI) framework?
keep in mind that a Lewis acid is a chemical species containing an empty orbital which is capable of accepting an electron pair to form a Lewis adduct. This means that, if no other differences are relevant (such as spatial factors or crystalline lattice organization), the strength of acidic Lewis sights resulting from metals in your zeolites should increase with the element's normal reduction potential. Be, anyway, very careful with this indication, as other factors may overcome it.
Actually I want to synthesis ZSM-5 with pure Bronsted and Pure Lewis acid sites separately. Do you think, Is it possible to synthesis these two catalysts with same metal ( i.e. Al or any other) via incorporation in their framework during hydrothermal treatment. or Can I synthesis these catalysts by Impregnation/Ion-exchange with particular metal to create desired type of acidity. In literature I found Sn, Ti, Zr, Hf have been used for Lewis acid sites, which metal I can use to generate pure Bronsted acid site (without LAS)?