I want to melt the polymer, but the viscosity of the polymer in the molten state is high. Is there a way to reduce the viscosity of the polymer melt (not the viscosity of the polymer solution)?
Dear Mahsa Mahdavinia, yes it is possible through the addition of additives such as plasticizers, lubricants, processing aids. If the polymer is not heat sensitive and mechanically stable, raising temperature and mixing shear may be another solutions. My Regards
Depending on the processing technique, and in addition to Abdulkader's answer, if you use injection or extrusion molding, the increasing extensional shear rate would destroy the entanglement of chains. This process would cause a viscosity drop due to the high shear rate.
I do not use injection molding or extrusion in my work. I just want the polymer to be melted without these processes and dispersed with the desired additives by ultrasonication. The problem is high viscosity and lack of ultrasonic wave movement.
Particle size reduction: If the polymer contains particles or aggregates that contribute to the high viscosity, consider implementing techniques like high-pressure homogenization or milling to reduce particle size. Smaller particle sizes can lead to reduced viscosity by decreasing the resistance to flow. (or)
Extended ultrasonication: If the initial ultrasonication duration does not lead to the desired viscosity reduction, consider extending the sonication time. However, be cautious of potential heat buildup during prolonged sonication, as it can cause degradation or other adverse effects. Monitor the solution temperature closely and ensure it remains within acceptable limits.