Argument: Had the entropy of the Universe been an actual observable, these erroneous estimates for total entropy would have been ruled out by observation alone.
Instead, each of the values Srelativistic and SBH were revised
when they were discovered to be subdominant in light of new theoretical knowledge
on the composition and the nature of interactions present in the Universe.
Proof: A good example of how entropy is not a measurable quantity can be found in the cosmologists’ evolving understanding of the Universe’s entropy, in recent decades
The first estimates of the (observable) Universe’s entropy date from around 1980
and stemmed from thermodynamics, attributing the bulk of the Universe’s entropy to
the blackbody radiation of the cosmic microwave background, Srelativistic ∼1090, expressed in natural units, G = c = ~ = kB = 1. Some years later the realisation that the
entropy of gravity could not be overlooked in the overall budget led to this value being
revised by Frautschi, and later firmed up by Penrose.
The conclusion is that the formation of supermassive black holes has led the gravitational contribution to today dominate over that from the microwave background by around 15 orders of magnitude, SBH ∼ 10104
More recently this estimate has had to be revised yet again to account for the fact
that the vacuum energy Λ dominates the Universe’s energy density today, so that the
corresponding entropy that Λ generates at the cosmic horizon has to be considered. It
turns out our previous estimate of the Universe’s entropy due to gravity is wrong yet
again, and altogether negligible when compared to the entropy of the vacuum which
dominates over the gravity value by a further twenty or so orders of magnitude, SΛ ∼
10124
The point here is, with the example of the evolving understanding of the
Universe’s entropy, illustrates the premise that the estimated entropy for a system is a function of the observer’s knowledge of the system.
References (proof & premise):
1. Biocosmology: Biology from a cosmological
perspective, Marina Cortˆes,1,2 Stuart A. Kauffman