TCT is a very useful index for estimating vegetation, albedo and wetness by using remotely sensed images. Recently a paper has been published about the derivation of these coefficients for at-sensor reflectance. The paper is freely available until the end of this year at this link:
http://www.tandfonline.com/eprint/Nq2wIHsHwmCFqhVTJNpf/full