The above relation has been used in the synchrotron cooling expression in the paper "Behaviour of dissipative accretion flows around black holes" 2007MNRAS.376.1659D.
We know that the electron thermal velocity is v_e = (k T_e/m_e)^0.5 and ion thermal velocity is v_i = (k T_i/m_i)^0.5. If we say that ions and electrons have same kinetic energy then...m_e (v_e^2) = m_i (v_i^2)...and we arrive at the ralation...
T_e = (m_e/m_i)T_i
But under what assumptions can we arrive at the relation T_e = (m_e/m_i)^0.5 T_i ??