Thank u Dr mandal. If u don't mind, can u post input file. I am new to Gaussian, hence not so expert. Moreover it does no't have an experimental geometry coordinates.
Sorry for Late reply. There is an option in Gaussian for Symmetry determination "Symm(PG=Group)". But I am not sure it works or not. Please test it. I hope you will not face any problem here. Because most probably, though CO2 and N2O possess Dinfh or Cinfv, Gaussian and other packages not uses the highest level of symmetry it always consider lower symmetry. In your case they are D2h and C2v. You can also test this. Hope this helps..