How to improve the utilization rate of hydrogen peroxide when doing oxidation reaction, in addition to general operations such as drop it slowly, adding hydrogen peroxide in batches?
The substrate of oxidation is 1,3- butanediol, glycerol, hexanediol.
The goal is to convert them to the corresponding ketones, acids.
Actually, you are asking two questions.
1. How to improve the selectivity?
2. How to improve the "atom efficiency?"
Both are discussed in tons of papers but there is no simple answer. The only solution is to optimize experimentally your own catalytic system. You can vary solvent, acidity, temperature, conversion, concentrations, etc. Surely, the nature of the catalyst is the major parameter.
use hydrogen peroxide-acetic acid mixture or more accurate per acetic acid
Shiv Kumar Yadav Alcohols undergo esterification in the presence of acetic acid.
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