I have carried out a hydrogen chemisorption experiment and have determined, from the linearized Langmuir isotherm, the volume of hydrogen required for mono layer coverage (i.e 5.5 ml/g). How do I calculate metallic dispersion from this value.
where S is a stoichiometric factor. That means for example in the case of Pt and H2 chemisorption, one molecule of H2 dissociate to to give two atoms to be chemisorbed each atom over Pt
N is the amount of monolayer, experimentally obtained from Langmuir isotherm (in static experiments) or directly from dynamic (flow experiments) in mol/g
M is the molecular weight of the metal (g/mol)
L is the weight percentage of metal in your solid. This value should be measured (for example by ICP). You should not use the theoretical percentage, I mean the percentage that you suppose after preparation.
where S is a stoichiometric factor. That means for example in the case of Pt and H2 chemisorption, one molecule of H2 dissociate to to give two atoms to be chemisorbed each atom over Pt
N is the amount of monolayer, experimentally obtained from Langmuir isotherm (in static experiments) or directly from dynamic (flow experiments) in mol/g
M is the molecular weight of the metal (g/mol)
L is the weight percentage of metal in your solid. This value should be measured (for example by ICP). You should not use the theoretical percentage, I mean the percentage that you suppose after preparation.