You can use ALD TiO2 deposition using tetrakis-dimethyl-amido titanium or Ti isopropoxide precursors and H2O. the reference to look at - http://scitation.aip.org/content/aip/journal/jap/102/8/10.1063/1.2798384.
Alternatively you can use e-beam evaporation of 1-2nm of Ti and oxidize it by exposure to air and repeat. the reference to look at -