Dear Abdelkader Bouaziz, thanks for your answer. I have searched these protocols before, and none of them are used to synthesize self-healing PVA/TA hydrogels. I found two papers that have worked on PVA/TA self-healing hydrogels, but it seems that their protocol is not complete.
So, I am searching for a true and complete protocol for synthesizing this hydrogel.
If you find a protocol, but it is not complete, maybe it is a patent already. You can look on EPO website, or use google patent to check it. You have to try several keywords to find patents, it is a bit exhaustive. Another idea is to reach the authors and ask for clarification (Also ask if they have a patent). Sometimes, it is the fastest way. Hope my suggestions are helpful, good luck. Have a nice day. Cheers