In Homoleptic iridium based complex synthesis. in second step of reaction the glycerol used as solvent. after the reaction the reaction mixture added to water. at extraction time the glycerol is completely not extracted. and not forming a solid. is there any way to remove glycerol and get solid.
Dear Aravid: See Russian Federation Patent 2093503. To reduce sludge is added to 10% silicone polymer and distilled with superheated steam under vacuum at a bottom temperature of 175-183 0C.
Dear all,
the best way is to extract your product instead of the reaction medium. Regards
It's quite hard to give you an answer if we don't know the solubility of your complex. You could try a extraction with ethyl ether, assuming your compound is soluble in ethyl ether. The solubility of glycerol in ether is very low.
- Badges
- Science topic