1 - using command " hold on/off'" you can plot n curves in a one figure and their difference where be shown,
2 - or you can plot their difference in a figure,
3- or using time based characteristics like Overshoot, Undershoot, rise time, settling time of 2 figures, you can show their difference of figures, even you can use ITAE index,
method 3 can be down without programming in editor,
If you want to fill an area between two curves, there is a discussion in the stackoverflow forum (http://stackoverflow.com/questions/6245626/matlab-filling-in-the-area-between-two-sets-of-data-lines-in-one-figure) which you need to read.
I am also not sure what exactly you want to do. Anyway, if you want to fill the area between two curves, you can use the comand 'area' in Matlab. You can check the help to know how to use it.