Due to PVA is soluble in water you can try to blend it with PEDOT: PSS.
Nanofibers of 3wt% of PVDF/PEDOT-PSSA in DMF have a electrical current of 2nA when 1V is applied. The current in the fiber can be increased incrementing the wt% of PEDOT that also enchance the fiber formation.
The effects of solution properties and polyelectrolyte on electrospinning of ultrafine poly(ethylene oxide) fibers. Polymer 2004;45:2959–66 and citing publications
doi:10.1016/j.polymer.2004.03.006
You can change or add a different solvent or, probably more straight forward, add salt.