please provide method and materials.
The publication you get here will help you:
https://www.researchgate.net/publication/237861923_Charge_transfer_complexes_of_diquat_and_paraquat_with_halide_anions
Article Charge transfer complexes of diquat and paraquat with halide anions
Other than METHOD 549.2 DETERMINATION OF DIQUAT AND PARAQUAT IN DRINKING WATER BY LIQUID-SOLID EXTRACTION AND HIGH PERFORMANCE LIQUID CHROMATOGRAPHY WITH ULTRAVIOLET DETECTION
www.epa.gov/microbes/documents/m_549_2.pdf
Use sodium dithionite in strong basic solution then detect blue color of the radical of paraquat.
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