Extract out the volatile principle using hydrodistillation method by clavenger assembly. Then check its bioactivity. If found active then go for GCMS identification of compounds.
The most potent method is the solvent extraction gradient in polarity and then measure the activity as antioxidants for example and followed by GC MS. Thanks
Essential oils isolated from aromatic plants (see the threads) by different methods and aroma compounds isolated by fractional distillation are biocompounds and have been reported to have antibacterial, antifungal, antiviral, insecticidal and pharmacological properties.