The mixing procedure depends on the matrix, the compatibility between graphene as a filler and the matrix is the key factor to determine the mixing procedure.
I did it with Al matrix. I mixed the graphene using ball milling. here is the link of the paper. it is a very promising technique for mixing graphene or any other graphetic structure materials. http://www.sciencedirect.com/science/article/pii/S1359836813007737
Please contact Prof. Lawrence Drzal at Michigan State University about your question. He is an expert in exfoliated graphene nano-platelets, and mixing them with polymer resins. He should be able to give you a detailed answer to your question. His email is [email protected].