GRACE data is not images. The GRACE satellite measures surface gravity changes. There are various GRACE solutions that you can use by coding in Python or MATLAB. For more information and GRACE data you can visit the following site:
If you want to use GRACE level 3 dataset which is projected on the spatial domain, I think that these dataset is not an image. I think that it is better to open the gridded dataset in MATLAB and save it as a Geotiff image. After that I think it is possible to open the image in ENVI. However, it should be noted that I am not an expert in ENVI and this is just an idea that I raised in response to your question.