The standard reduction potential of Fe(III)/Fe(0) is -0.037 V / SHE and that of Fe(III)/Fe(II) is 0.771 V.

Therefore, in cyclic voltammetry does the direct reduction of Fe(III) to Fe(0) occur near the -0.037 V?

Otherwise, does Fe(II) state must be go through so the reduction reaction does not happen?

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