Dear Ankit kumar Srivastava,

Find in attach, a paper on:Positively Charged Pd, Complexes of a New Thiophenoxide-hinged Binucleating Ligand. The Crystal and Molecular Structure of

p-{4- Methyl-2.6- bis[2- (2-pyridyl -xN)ethyl imi no-KN-met hyl] thiophenolato-

1 KS : 2~S}-bis[dichloropalladium(ii)] Chloride-Water-Methanol (1 /I /0.5) t

Bernard F. Hoskins, Christine J. McKenzie, Richard Robson," and Lu Zhenrong

Department of Inorganic Chemistry, The University of Melbourne, Parkville, Victoria 3052, Australia

You find in it: the instu generation of 2,6-Diformyl-4-methylthiophenol from compound I.

Best wishes

In attach a paper you find in it : 2,6-diformyl-4-methyl-thiophenol, generated in situ by hydrolysis of (5>(2,6-diformyl-4-methyl[8]

 Reference (8) a) J. G. Hughes, R. Robson, Inorg. Chim. Acta 35,

87 (1979); b) A. M. Bond, M. Haga, I. S. Creece,

R. Robson, J. C. Wilson, Inorg. Chem. 28, 559

(1989); c) B. F. Hoskins, C. J. McKenzie, R. Robson,

L. Zhenrong, J. Chem. Soc., Dalton Trans. 2637

(1990); d) B. F. Hoskins, R. Robson, G. A. Williams,

J. C. Wilson, Inorg. Chem. 30,4160 (1991).phenyl)dimethyl thiocarbamate

SIR ,i was trying to find the starting material 2- (N,N-dimethylcarbamoylthio) -5-methylisophthaldehyde in sigma aldrich . but i did not get it. what should i do

Please, see link: https://www.google.com.eg/url?sa=t&rct=j&q=&esrc=s&source=web&cd=1&cad=rja&uact=8&ved=0ahUKEwj2seWJyvHOAhVHCsAKHc3DCOIQFggaMAA&url=http%3A%2F%2Fwww.chemicalbook.com%2FChemicalProductProperty_EN_CB93073510.htm&usg=AFQjCNHs9P5UB5zqxunP0pE7p-lmzjmWKA&sig2=uUy-ipLtcqG48hcqGHgANg

CAS No. 88791-04-2

Chemical Name: 2-(N,N-dimethylcarbamoylthio)-3-methoxybenzaldehyde

Synonyms: 2-(N,N-dimethylcarbamoylthio)-3-methoxybenzaldehyde

CBNumber: CB93073510

See also:

https://www.google.com.eg/url?sa=t&rct=j&q=&esrc=s&source=web&cd=2&cad=rja&uact=8&ved=0ahUKEwj2seWJyvHOAhVHCsAKHc3DCOIQFggfMAE&url=http%3A%2F%2Fwww.chemicalbook.com%2FProductChemicalPropertiesCB93073510.htm&usg=AFQjCNHu0fsht4ESFHX2d_X3ZqhCrBsraQ&sig2=-tsXB803HR6tds-xTVuu1g

2-(N,N-dimethylcarbamoylthio)-3-methoxybenzaldehyde

Name: 2-(N,N-dimethylcarbamoylthio)-3-methoxybenzaldehyde

Catalog Number: DA-27622

CAS: 88791-04-2

Formula: C11H13NO3S

Formula Weight: 239.29082

Purity: 95+%