Far as we know (which is very little), Titan doesn't harbor life (the life we know), but has two strong (Earth Life) biosignatures N2 98% and CH4 2%. As far as we know, abiotic processes occurred on Titan Atmosphere formation. On Earth, the only planet that has life, we have N2 78%, O2 21% and CH4 ~1.9 ppm. Both the N2 and mainly CH4, are out of geochemical equilibrium by the biological production.
What should we know about "Life" in our Solar System? What could know about "Life" in the nearest stars?
If a hypothetical spectrometer was placed in Alpha Centauri and headed toward Titan transit, What would be our conclusions?