Si generally form native oxide layer (SiO2) in an open atmosphere. Can anyone tell me only organic treatment (2-propanol) can generate OH terminal group on this surface without any chemical and/or physical treatments?
Si(OH)4 generates two molecules of water and formed SiO2. On the surface can be OSi(OH)2 or H2SiO3. Silica gel is used for moisture removal. Perhaps, propanol- 2 generate molecules water via SiO2. Acetone molecules obtained.
My hypothesis is based on the experience and my knowledge. Sources look for yourself. Ask Deep Chand Agrawal . The same question he asked. SIlica gel column becomes black while packing with cyclohexane. Why? Perhaps this experiment will be enough for you ?
Oxidation in presence of water (humidity) will not take place without the influence of water. If you have an intermediate “Si(OH)” state why you shouldn’t have native OH groups onto the surface of the amorphous SiO2 surface. Water itself is able to influence such surfaces, as demonstrated within the publication.