I'm not sure of the dimensions that you are seeking. Sterlitech carries a pretty good assortment of disc membranes for testing (http://www.sterlitech.com/filters/membrane-disc-filters.html), but I am not sure of the thickness. I suspect that a membrane material that thin will be attached to a supportive layer of material.
Gore (makers of Gore-Tex) also have some nice ePTFE membranes for filtration: http://www.gore.com/en_xx/products/filtration/microelectronic/upw/ultrapure-membrane-technology.html
Dupont Teijin films makes PET and PEN films below 6 µm (1/4 mil). For the thinnest films, look into Mylar and Teonex for capacitors, some of which go down to 0.9µm.