Are the dative bond electrons less localized than other covalent bond electrons, since the dative bond electrons come from same atom and the other atom handles extra electron.?
The answer there is no difference between a dative and covalent bonds:
A covalent bond is formed by two atoms sharing a pair of electrons. The atoms are held together because the electron pair is attracted by both of the nuclei. In the formation of a simple covalent bond, each atom supplies one electron to the bond - but that does not have to be the case. A coordinate bond (also called a dative covalent bond) is a covalent bond (a shared pair of electrons) in which both electrons come from the same atom.
Examples:
The reaction between ammonia and hydrogen chloride
If these colorless gases are allowed to mix, a thick white smoke of solid ammonium chloride is formed. Ammonium ions, NH4+, are formed by the transfer of a hydrogen ion (a proton) from the hydrogen chloride molecule to the lone pair of electrons on the ammonia molecule.
When the ammonium ion, NH4+, is formed, the fourth hydrogen is attached by a dative covalent bond, because only the hydrogen's nucleus is transferred from the chlorine to the nitrogen. The hydrogen's electron is left behind on the chlorine to form a negative chloride ion. Once the ammonium ion has been formed it is impossible to tell any difference between the dative covalent and the ordinary covalent bonds. Although the electrons are shown differently in the diagram, there is no difference between them in reality.
Example: Dissolving HCl(g)HCl(g) in Water to make Hydrochloric Acid
Something similar happens. A hydrogen ion (H+) is transferred from the chlorine to one of the lone pairs on the oxygen atom.
H2O+HCl→H3O++Cl−H2O+HCl→H3O++Cl−
The H3O+ ion is variously called the hydroxonium ion, the hydronium ion or the oxonium ion. In an introductory chemistry course, whenever you have talked about hydrogen ions (for example in acids), you have actually been talking about the hydroxonium ion. A raw hydrogen ion is simply a proton, and is far too reactive to exist on its own in a test tube.
If you write the hydrogen ion as H+(aq), the "(aq)" represents the water molecule that the hydrogen ion is attached to. When it reacts with something (an alkali, for example), the hydrogen ion simply becomes detached from the water molecule again. Note that once the coordinate bond has been set up, all the hydrogens attached to the oxygen are exactly equivalent. When a hydrogen ion breaks away again, it could be any of the three.
The bonding in hydrated metal ions
Water molecules are strongly attracted to ions in solution - the water molecules clustering around the positive or negative ions. In many cases, the attractions are so great that formal bonds are made, and this is true of almost all positive metal ions. Ions with water molecules attached are described as hydrated ions.
Although aluminum chloride is a covalent compound, when it dissolves in water, ions are produced. Six water molecules bond to the aluminum to give an ion with the formula Al(H2O)63+. It's called the hexaaquaaluminum complex ion with as six ("hexa") water molecules ("aqua") wrapped around an aluminum ion. The bonding in this (and the similar ions formed by the great majority of other metals) is coordinate (dative covalent) using lone pairs on the water molecules.
The electron configurtin of luminum is 1s22s22p63s23px1. When it forms an Al3+ ion it loses the 3-level electrons to leave 1s22s22p6. That means that all the 3-level orbitals are now empty. The aluminum reorganizes (hybridizes) six of these (the 3s, three 3p, and two 3d) to produce six new orbitals all with the same energy. These six hybrid orbitals accept lone pairs from six water molecules.
You might wonder why it chooses to use six orbitals rather than four or eight or whatever. Six is the maximum number of water molecules it is possible to fit around an aluminum ion (and most other metal ions). By making the maximum number of bonds, it releases most energy and is the most energetically stable.
Only one lone pair is shown on each water molecule. The other lone pair is pointing away from the aluminum and so is not involved in the bonding.
Because of the movement of electrons towards the center of the ion, the 3+ charge is no longer located entirely on the aluminum, but is now spread over the whole of the ion. Note: Dotted arrows represent lone pairs coming from water molecules behind the plane of the screen or paper. Wedge shaped arrows represent bonds from water molecules in front of the plane of the screen or paper.
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