PET is insoluble in water, diethyl ether, and many common organic solvents. However, it is soluble in DMSO, nitrobenzene, phenol, and o-chlorophenol. The reforming can be done with fixed bed reactor using Ni over La2O3-Al2O3 support with temperature 700 degree C to 800 degree Cent. PET can be efficiently converted to hydrogen and valuable fuels at optimized condition. Production of hydrogen from plastic waste could be a prospective key to the ecological problems resulted from waste.the steam reforming of Polyethylene terephthalate (PET) dissolved in phenol can be conducted in a fixed bed reactor using above mentioned catalyst.