If you want to collect pollen from the plants, the best way is to collect the plant with its flower and put it inside a half folded paper. The paper will absorb the moist and the plant is dry after a few days. Then you should take a sample from the anther of the flower and acetolyze it. Acetolysis is the only treatment needed for pollen analysis of the plant samples.
A benefit of this method is that the plant can be preserved for many years and whenever needed a pollen sample can be collected from the plant. Additionally the plant can be accurately identified by botanists if it you do not know the plant.
I guess by collection using brush at the anthesis time, but authors of this paper can perhaps answer it best if you mail/ phone them- Data Pollen Analysis in Honeys Collected from Karnataka Region of...
, I will also check with Prof. Sagar Pandit & Ankur Patwardhan