Is the pH value will affect the calculated overpotential in OER process by DFT?

It is noted that for OER process, the Gibbs reaction free energy is defined by 𝛥𝐺 = 𝛥𝐸 + 𝛥𝑍𝑃𝐸 − 𝑇𝛥𝑆 + 𝛥𝐺U + 𝛥𝐺PH where the last term is the pH value correction. 𝛥𝐺PH=pH×kBTln10. How this term...

28 November 2020 1,649 2 View