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Questions related from Nicolas Neuman
In my experience doing cyclic voltammetry glassy carbon (GC) can be used up to 1.8-2.0 V vs. Ag/AgCl in MeCN water mixtures, without visible degradation of the electrodes. For graphite electrodes...
26 March 2021 6,126 1 View
I have prepared a Co(III)corrole, and the NMR in DCCl3 shows broad signals between 7.30 and 9 ppm. I've read that Co(III)corroles are paramagnetic with S = 1. So I attempted to add MeCN to...
27 April 2017 1,550 6 View
Does anyone know of a paper where the formal oxidation potential of H2O to O2 in non-aqueous solvents, specially propylene carbonate and acetonitrile, has been measured or estimated?
09 April 2015 1,397 3 View
The rhombograms for the effective g-factors of Fe(III) allow to calculate these factors knowing the rhombicity E/D parameter and viceversa. But are there analytical formulas (perturbative for...
10 March 2015 7,240 5 View
I've done 20 gauss, 4-second repetitive scans with a Bruker EMX-Plus EPR spectrometer, to follow the kinetics of a generated organic radical. The equipment has an approximately one second delay...
17 December 2014 7,359 3 View
Also If anyone has done it and has some advice, they would be welcome! Thank you
21 November 2014 5,357 3 View
I have a discrepancy with some published spectra but NMR data indicates we've obtained it almost pure
22 July 2014 6,917 2 View
