In transition metal oxides like LaTiO3, the Ti XPS spectra shows multi-component peaks. For example, in addition to the Ti d1 peaks, peaks for Ti d0 and d2 are also observed. These additional peaks are ascribed to the "final state effect". Now if I want to calculate the atomic percent ratio of La:Ti, I would normally take the ratio of the peak areas of La_3d and Ti_2p normalized by their respective RSF. So now my confusion is, while taking the area for Ti_2p should I also include the area of Ti d0 and d2 peaks or should I just consider the Ti d1 peak. Thank you in advance.