I am using biochar for adsorption of heavy metals. Experts are suggesting to activate the biochar through acid or base treatment. what are the benefits of activation? How does it improve heavy metal adsorption? Please provide some related litrature.
Briefly, the influence of activation depends on a variety of parameters. For instance; The raw material of adsorbent, the method of activation, the temperature/kind of chemical activator, the time of activation, to name but a few.
You can take a look on a lot of paper, review-paper, and chapters which have been published in recent years, and compare the effects of different parameters on the improvement of adsorbent after activation. Though in general, mostly activation has a tremendous effect on the surface-to-volume ratio of adsorption; therefore will have a great effect on adsorption efficiency.
As you may know the difference between activated carbon and carbon itself is that activated carbon is a porous material and has pores in comparison with carbon structure. There are different pores in size in activated carbon structure including mesopores and micropores. By using activated carbon for absorbing materials you may have better absorbance because of the pores in the structure.
Various modification methods have been developed in recent years to further enhance the sorption ability of biochar. Research has suggested that chemical modification could increase the number of functional groups, BET and surface porosity on the surfaces of biochar and enhance metals adsorption capacity.