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Inorganic Chemistry (2003), 42(4), 1140-1150.  

thankyou

Shaima

Please clear up your request (by equation ....) so I may be able to help.

Good luck

Dear Shaima Ibraheem Chyad Al-khazraji, I agree with Adel Amer in that your question is rather vague. I you are still interested in satisfactory answer, please provide a few more details.

Iwant any one know about techniques used for synthesis derivative compounds from dimethyl dichloro silane with aromatic aldehydes or aromatic carboxylic , Iwant paper& methods for synthesis.

Dear Shaima Ibraheem Chyad Al-khazraji, I found a reference indicating that Me2SiCl2 does not react with benzaldehyde. The statement is marked in yellow in the attached pdf.

Dear Shaima Ibraheem Chyad Al-khazraji, cited below is an article describing the reaction of chlorosilanes with aromatic aldehydes.

Article Reaction of benzaldehyde with alkyl(aryl)chlorosilanes

As for the carboxylic acids, thus far I only found the attached reference.

The reaction of benzaldehyde with alkyl(aryl)dichlorosilane

I can't open cited? I don't know what's the reason?

Dear Shaima Ibraheem Chyad Al-khazraji , the reason is that the article is rather old (1966) and that it was originally published in a Russian journal. Attached please find a pdf of the original article. I hope you will find it useful.

P.S. If someone helps you by answering your questions on RG, it is polite to recommend those questions.

thanks

I NEED new that the article reaction of dimethyldichlorosilane with aromatic aldehydes or aromatic carboxylic and application derivative .

Al-Khazraji

For the reaction of dichlorodimethylsilane with aldehydes see these references

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Al-kazraji

For the reaction of dichlorodimethylsilane with carboxylic acid see these references

OR

Preparation of dimethylsilanediyl diaalkanate II To a slurry of sodium alkanoate (8.2 g, 100 mmol, 2.0 equiv.) in anhydrous diethyl ether (40 mL) was slowly added a solution of dimethyldichloro silane I (6.45 g, 50 mmol, 1.0 equiv.) in anhydrous diethyl ether (10 mL). After addition was completed, the mixture was heated at reflux for 2 hours, and then filtered under N2. The filtrate was concentrated under vacuum at 40 °C to give dialkanoate II.

--- Chao, JianhuaFrom PCT Int. Appl., 2013090799, 20 Jun 2013

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Al-khazraji

For Aromatic carboxylic acid, see #5

For Aromatic aldehyde, see #6

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