In all the EDS(EDX) spectrums I have seen in different articles, there is a sharp peak in zero (KeV) . I had an EDX of my sample ,and there was a sharp peak at zero (KeV) ,too. But for my sample, it was defined that the peak was for Cl (Chlorine) ,which i don't think so .Because there was only a trace of Chlorine in my sample.