I think that no. The first record of Isidade is Cretaceous although the first record of octocorals could be oldest. May be Cambrian (Ausich & Babcock, 1998; Taylor et al., 2013), Early Ordovician (Lindström, 1978; Cope, 2005), Silurian (Bengtson, 1981) or even Ediacaran (McMennamin, 1998), the earliest known spiculate alcyonaria is Atractosella, from the Llandovery-Wenlock of Gotland (Sweden). Nevertheless, most alcyonarian remains are from the Cretaceous and Cenozoic (Bayer, 1956; Nudds & Löser, 2001). I recommend to you Cope (2005) and Bayer (1956) to control the most part of the bibliography about that.
As far as I know, there is no unequivocal record of Pre-Cretaceous Isididae ... Please cf. also some Recent "primary papers" by Schlagintweit & Gawlick 2009: The incertae sedis Carpathoporella Dragastan, 1995, from the Lower Cretaceous of Albania: skeletal elements (sclerites, internodes/branches, holdfasts) of colonial octocorals. Facies 55: 553-573 or Helm & Schülke 2003: An almost complete specimen of the Late Cretaceous (Campanian) octocoral "Isis" ramosa Voigt (Gorgonacea) from the Lower Saxony Basin, northwest Germany. Cretaceous Research 24: 35-40. Both are available online ...