What is the meaning of D peak shifting, and D peak FWHM changing in Raman spectra of DLC (a-C:H) films??

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Karamjyoti Panigrahi

I think this article help you. Let me know whether this article is helpful or not.

Arezou Zarei

Hello. When you have D lines at Raman of H-DLC substrates you must have a peak about 1350-1417 cm-1 .Shifting towards higher frequency or lower one will take place if you use different conditions. for example time, temperature, etc.

It's obvious that your shifts are because of time of scanning and maybe because of hotspots in your sample.