Magnesium-rich orthopyroxenes and calcium-rich clinopyroxenes are important constituents of basalts, gabbros, peridotites, and norites. They are the major minerals in pyroxenites. Magnesium-rich orthopyroxenes occur in the earlier-formed rocks of layered ultramafic complexes.
Iron-rich orthopyroxenes are found in metamorphosed iron formations in association with the amphibole grunerite. At higher grades of regional metamorphism, the amphibole anthophyllite breaks down to form magnesium-iron orthopyroxenes. The orthopyroxene enstatite occurs in high-temperature and high-pressure granulite facies rocks such as quartz-rich, garnet-bearing granulites.
The key differences between metamorphic and igneous orthopyroxenes are primarily related to their formation processes and resulting chemical compositions:
Formation Process:Metamorphic Orthopyroxenes: These form under high pressure and temperature conditions during the metamorphism of pre-existing rocks. They are typically found in high-grade metamorphic rocks such as granulites and charnockites1. Igneous Orthopyroxenes: These crystallize directly from magma and are commonly found in igneous rocks like norites, gabbros, and some ultramafic rocks1.
Chemical Composition:Metamorphic Orthopyroxenes: Often show compositional zoning due to changes in pressure and temperature during their growth. They may also exhibit re-equilibration features, reflecting the dynamic conditions of metamorphism2. Igneous Orthopyroxenes: Generally have a more uniform composition, reflecting the relatively stable conditions of crystallization from a cooling magma. They are typically richer in magnesium and iron2.
Inclusions and Textures:Metamorphic Orthopyroxenes: Frequently contain inclusions of other minerals that were present in the rock before metamorphism. These inclusions can sometimes appear rotated or deformed, indicating dynamic metamorphic conditions1. Igneous Orthopyroxenes: May also contain inclusions, but these are typically minerals that crystallized from the same magma. The textures are usually more uniform and less deformed compared to their metamorphic counterparts1.
These differences are crucial for geologists when interpreting the geological history and conditions of rock formation.
Dear Massoud Rahimpour: let me add that the metamorphic orthopyroxene (which used to be called hypersthene) is Fe rich, but also can have important proportions of Mn, this is quite obvious when the pleochroic scheme of the mineral goes from green to pink, as it happens in the orthopyroxene in the Imataca Complex (granulites and charnockites), located in the northern edge of the Guiana Shield, in Venezuela. These rocks, probably of volcanic origin, underwent Neoarchean granulitic metamorphism some 2,8-2,7 Ga ago), Regards, Sebastian.