The figure presents that CsPbI3 shows the high and low e2 at the low-E and high-E regions, respectively. It means that the band structure of CsPbI3 has a preference to have many inter-band transitions at the low E. On the other hand, both other systems show the (almost) balanced e2 over the wide E range. Hence, all the system might have similar maximum number of electrons involved in the transition (Nmax).
Please check the effective electron number (Neff). The formula is mentioned inArticle Electronic structure, chemical bonding, and optical properti...
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We can find Nmax as Neff reaches its saturation. If you find the Nmax of all the systems are similar, the suggestion above might be true.
At high energies, the response is due to the electron transitions from mixed s valence state of pb and p valence state of halogens to the mixed p conduction state of Pb and d and p conduction states of Cs
DOS of the CsPbCl3 at valence band is higher, does not mean more electron transitions? Do you think this might be involved?
I suggest that it might be involved. The more states (higher DOS) in the valence band should induce the more transitions, i.e., higher e2, mainly at the low-E region.