Your classifier does not show good performance. Therefore, I recommend checking another metrics, like "Kappa statistic", before reconfiguring LibSVM's parameters, or even trying other classifiers. You may need also to check your data characteristics.
Recall is (true positives)/(true positives + false negatives). If this is 100%, you must have zero false negatives, so in that respect your classifier is working well.
Precision is (true positives)/(true positives + false positives). If this is 6%, you must have many more false positives than true positives, so in this respect your classifier is very weak.
In summary, if you don't care about false positives you have a strong classifier. If you do care then your classifier is very weak.
You may check the below attached paper which handles all the above classification parameters over a real life review data set.....I hope it will help you to clarify your doubt.....