Greetings. Briefly: semiconductors (Ge, Si, A3B5, A4B4 ..., etc.) have their own (i) conductivity in "pure" form: for a particular crystal, everything depends on the presence or absence of an impurity: donor n--,n-,n, n +, n ++ (for example, P ) or acceptor p--,p-,p, p +, p ++ (for example, B) or combinations thereof. The type of electrical conductivity of a semiconductor sample (n or p) can be determined from experience using the Hall effect.
It depends on your fabrication technique. If you use any PVD method like sputtering, it will appear as n-type. If you use cbd or exfoliation, you may get p-type.