Dear crystallography community,
in compounds which containing F- and O2- anions I think usually the O2- prefere a tetrahedral environment and the F- a triangle of cations. If you want to write "O2- prefere the tetrahedron and F- the triangle" in a manuscript, some references are needed.
So my question is, do somebody know a review article about coordinationsnumbers in ionic solid state compounds, which could be cited?
Best regards from Germany
The coordination number rule and its implications – a review
Article The coordination number rule and its implications – a review
“Sizes” of atomic and molecular species, their dependence on the type of interaction with other ones and on their general embedment in a structured collective have ever been important topoi of scientific debate in crystal chemistry. Going along with various definitions of size different views on its effect on structuring the surroundings of an atom or ion have developed which were biased by the “parentage” of the scientists from a particular field of their scientific discipline. Even the description of “surroundings” was ambiguous in many cases, the question “who is neighbour or not” or “who interacts with a central atom and to which degree” has led to many debates in literature of which we may mention only one as a representative.1 Rudolf Hoppe has contributed to this discussion in a beneficial way by denominating the ambiguities2 and by giving help to overcome them.3 The concept of “coordination” has been of greatest importance in his theoretical work but also in the vast output of his synthetical achievements. As another highlight we may remember his efforts to study the interdependency of topology and energy by bringing Madelung – type contributions into closer attention of crystal chemists. And there too coordination numbers and their definition have played a decisive role in some of his “shortcut” approaches to calculate the electrostatic part of lattice energy.4 He has even used such calculations to point at possible errors in structure determinations, though this has not always helped him to avoid some shortcomings in the crystallographic work on his compounds.
Hello
you can see these articles:
https://en.wikipedia.org/wiki/Coordination_number
https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Supplemental_Modules_and_Websites_(Inorganic_Chemistry)/Coordination_Chemistry/Structure_and_Nomenclature_of_Coordination_Compounds/Coordination_Numbers_and_Geometry
Article Coordination Numbers of Central Atoms in Coordination Compounds
Introduction to Coordination Chemistry (Inorganic Chemistry: A Textbook Series) by Geoffrey A. Lawrance | Mar 15, 2013
Essentials of Coordination Chemistry: A Simplified Approach with 3D Visuals 1st Edition, Kindle Edition by Vasishta Bhatt (Author)
Coordination Chemistry by Joan Ribas Gispert (Author)
Concise Coordination Chemistry Paperback – 1 January 2008 by R. Gopalan (Author), V. Ramalingam (Author)
- Badges
- Science topic
- Similar topics
- Phytochemistry
- Extracts