When I made the analysis GC-MS of an essential oil, I found as majority product the 1-Chloromethyl-1-(3,5-dimethylcyclohexyloxy)-1-silacyclohexane is that possible and logic the presence of sila (metal Si)
SILICA Minerals are present throughout the cell walls of plants. Therefore, it is expected that a small percentage of Si will be detected when analyzing as essential oil by GC-MS.
For more on the presence of Si compounds with organic compounds extracted from plants, please see the following link:
Some vegetables contain colloidal silica but it is very doubtful that the silicon compound you suspected can be present in an essential oil. Your GC-MS assignment is likely to be wrong.
I strongly suspect that the library search has given a wrong identification. However, it is possible that the chemical class is correct. In such case it may derive from the siloxanes of the column stationary phase