Ash content could be determined indirectly by determining organic matter content and obtaining total ash as 100 - Nirs predicted organic matter.
In my understanding, calcium and phosphorus will no be possible to determine via NIRS as this technique is not able to interact with these elements unless they have an organic component, which would not be the case of all Ca and P in your samples
Without prejudice to the company and its analysis, P determination by NIR is not easy. To date, we are not certain of our calibrations and hence the results of NIR determinations of P.
You may wish to contact Prof G. Batten, Editor in Chief, Journal of Near Infrared Spectroscopy. He is a very helpful person.