There are 3 sub questions below:
1. Suggest your own answer:
This paper seems to suggest that both laws are not operating in the same set. http://link.springer.com/article/10.1007/s10701-007-9159-z ArXiv link: http://arxiv.org/ftp/cond-mat/papers/0703/0703235.pdf
If possible, please don't bring in the black hole information paradox, as the paradox is an exercise of the application of the fundamental issue of this question. Unless the example is illuminating with specific assumptions clearly laid out. For example:
2. Do you agree with this?
This paper suggests that:
http://arxiv.org/pdf/1009.5111v3.pdf
We postulate that all kinds of information, in general, about a physical system fall
into two categories. Let’s call them Π1 and Π2 (Π is the first letter of the Greek word that stands for information). The Π1 class contains the most fundamental information that defines a particle, such as the mass, the electric and magnetic charge and the angular momentum of it. The much larger Π2 category includes information about how particles mingle with each other and the properties that rise from their combinations. A book, for example, contains a vast amount of Π1-info about the aforementioned conserved quantities, of the elementary particles it consists of, and an even larger amount of Π2-info about how these particles unite to form different nucleons, atoms and molecules including also the way all these combine to form letters and words that mean something.
So Unitarity is preserving Π1 information and the second law is destroying Π2 information.
3. Please clarify if information is lost when going from the pure to mixed state. If so, why do we believe in unitarity?
http://arxiv.org/pdf/1009.5111v3.pdf, http://arxiv.org/ftp/cond-mat/papers/0703/0703235.pdf