I'm going to assume that you mean HEPPS, CAS 16052-06-5. (It's a common bad habit on this site to save a few keystrokes and waste other people's time on needless searches.)
Anyway, if it's indeed HEPPS then DTPA will almost certainly dissolve in the 200 mM HEPPS solution. However, you may have difficulty in preparing a 5 mM DTPA solution in water. Solubility at room temperature is a bit below that; see dx.doi.org/10.1021/je100797b |J. Chem. Eng. Data 2011, 56, 437–443. So, if you intended to make two solutions and mix them you may have a problem reaching 5 mM DTPA.