How to synthesis a poly AM with ATRP usin CuCl and PMDETA as a ligan and Benzyl bromide as initiator?

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Mathias Glassner

I doubt that the combination of monomer (I guess AM is acryl amide) ligand and initiator you propose will work well. This link might be helpful:

https://www.cmu.edu/maty/atrp-how/monomers/other-monomers.html#amides

Gergely Kali

The system you described can work. Which solvent would you use? You have to take care to remove the oxygen from the system.

You can check: M. Teodorescu, K. Matyjaszewski. Atom Transfer Radical Polymerization of (Meth)acrylamides, Macromolecules, 1999, 32,4826–4831.

Agaguena Amel

i have use toluen as solvent but i havn't a good conversion???? and i can't dilute the polymer with THF ?????