I need to define faults, volcanic emission centers and structural lineaments from Google Earth. In what do I have to be careful with, in order to avoid mistakes due, for example, to the topography?
Really this is a complicated question in that there are rather a lot of variables and things to look out for.
I would sum up the main concerns to consist of interpreter experience (have you done this before etc...), the image data used (what imagery are you using, geology maps already published), and the guidelines (scale, type of map etc) laid out.
Data
Before you start have you looked at using something like OneGeology WMS feed to better inform the location you are looking at. This will include information that has already been mapped by national geological agencies.
Furthermore, in what climatic environment is the investigated area being studied? (i.e. Tropical Jungle vs Desert environments). In this regard I would look to see what has been done before see how pronounced features have been interpreted and categorise from there.
Experience
If you will go down the raw interpreting satellite imagery (not radar) to derive faults, volcanic emission centres and structural lineaments. Things to be aware of including the very nature of geological interpretation being partly subjective and therefore results should be confirmed with field experience however, if this can't be done then you should just bear in mind experience in geological interpretation is important...
Have a look at this paper which might help: http://www.gsm.org.my/products/702001-100335-PDF.pdf
You can easily detect faults or any other geological structural features using DEM derived shaded relief map. More accurate results come for higher resolution data-sets. However, extracting lineaments from google earth is not recommended cause many regions are characterized by dense vegetation or some other land-use pattern (Such as agriculture).
Accurate and reliable extraction is easier through terrain model. The disadvantage of extraction of lineaments using these data sets is that you can not discriminate which are truly geological structures and which are some other features (eg. geomorphic lineaments, man-made canals etc.). Therefore, a very extensive fieldwork is require to identify the geological features.
Here, I've attached my article recently published in Arabian Journal of Geosciences, maybe help you for your study.