Perovskite (ABO3) A-O bond Length is 40% greater than B-O bond length. How does one calculate the bond length?
x-ray or neutron diffraction.
You can collect the x-ray powder diffraction pattern and by the structural refinement you can find the bond lengths
not for oxygen. The scattering cross section is too small, which is why neutrons are used to get precise locations of oxygen in the unit cell (As well as site occupancy). Of course using both and refining them together is even better!
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