I have prepared a solution of polymer, PQT-12 in chloroform. And also done sonication for 5 minutes. We have seen large particles in the film after deposition. Why did I get these large particles?
After depositing the solution on glass, by eye only it was visible that few bigger particle was there. When I was discuss with few polymer researcher, they told, "Don't do ultrasonication with polymer". But many authors have reported ultrasonication of polymer in their papers. What are the advantages of ultrasonication with polymer??
Most probably it happens due to chain-breakage into radicals - with further recombination - which results in crosslinking, swelling of the network formed -- and as a final result -----> gel-formation
I agree with Leonid. In ultrasonic bath the bubbles of various sizes break together and the temperature at the tiny region can go as high as 5000K. This is the reason for chain breaking/bond breaking and production of radicals which can react together to make crosslink and become insoluble. You get particles separating at the bottom.
The using of ultrasonication on the preparation of polymer have several advantages depending on the nature of solvent ,the temp. and the time exposure.